Malaysian
Journal of Analytical Sciences Vol 26 No 2
(2022): 399 - 414
Initiatives in
utilizing natural reagents and natural materials for chemical analysis: Talent and challenge for ASEAN in new normal chemical analysis
(Inisiatif dalam Penggunaan
Reagen Semulajadi dan Bahan Semulajadi bagi Analisis Kimia: Bakat dan Cabaran
untuk ASEAN dalam Analisis Kimia Norma Baru)
Kanokwan Kiwfo1,2, Pei Meng Woi3*, Chalermpong
Saenjum1,2,4, Treethip Sukkho1,2,4, Kate Grudpan1,2,5
1Center of Excellence for Innovation in Analytical Science
and Technology
2Cluster of Excellence on Biodiversity-based Economic and
Society (B.BES-CMU)
Chiang Mai University, Chiang Mai 50200, Thailand
3Chemistry Department,
Faculty of Science, Universiti Malaya, 50603 Kuala Lumpur,
Malaysia
4Pharmaceutical Sciences, Faculty of Pharmacy
5Department of Chemistry, Faculty of Science
Chiang Mai University, Chiang Mai 50200, Thailand
*Corresponding
author: pmwoi@um.edu.my
Received: 19 September 2021; Accepted: 28 November 2021; Published: 28 April 2022
Abstract
This review explores the contributions of
natural resources with diverse disciplines which offers the insights into the
design of greener chemical analysis. The discussion was focused on the
published works in our group where a diverse range of natural reagents used in
the determination of various environmental analytes has been highlighted,
aiming to discuss the initiatives and applicability of the usage of alternative
natural reagents and substitute synthetic methods in optimizing analytical
processes, which in turn would lead to cost-effective and time-efficient in
handling analytes assay. By exploring the potential of natural reagents, the
sustainability in green chemical analysis could be promised in coming near
future, especially in convincing for the talent and challenge for ASEAN in this
new normal chemical analysis.
Keywords:
green
analytical chemistry, natural reagent, natural material, local wisdom,
sustainable chemistry
Abstrak
Ulasan
ini membincangkan sumbangan reagen semula jadi dalam pelbagai disiplin ilmu
yang dapat memberikan gambaran mengenai analisis kimia hijau. Perbincangan in
fokus kepada penerbitan yang telah diterbitkan oleh kumpulan kami di mana
beberapa jenis reagen semula jadi yang digunakan dalam penentuan pelbagai
analit persekitaran akan diutamakan, bagi membincangkan inisiatif dan penerapan
penggunaan reagen semulajadi alternatif dan kaedah sintetik gantian dalam
mengoptimumkan proses analisis, supaya analisis dapat dikendalikan secara kos
efektif dan cekap masa. Dengan menerokai potensi reagen semula jadi,
kesinambungan dalam analisis kimia hijau akan dapat dijanjikan dalam masa
terdekat terutamanya dapat memberikan keyakinan dalam bakat dan cabaran di
ASEAN dari segi analisis kimia di norma baru ini.
Kata
kunci: kimia analisis
hijau, reagen semula jadi, bahan semula jadi, kebijaksaan tempatan, kimia
kelestarian
Graphical Abstract
References
1. Anastas, P. and Eghbali, N. (2010). Green
chemistry: principles and practice. Chemical
Society Reviews, 39(1): 301-312.
2. Abdussalam-Mohammed, W., Qasem Ali, A. and
Errayes, A. O. (2020). Green Chemistry: principles, applications, and
disadvantages. Chemical Methodologies, 4(4):
408-423.
3. OECD (2021). Sustainable chemistry. Access from https://www.oecd.org/chemicalsafety/risk-management/sustainablechemistry.htm
[Retrieved 13 September 2021].
4. Gamal, M., Naguib, I. A., Panda, D. S. and
Abdallah, F. F. (2021). Comparative study of four greenness assessment tools
for selection of greenest analytical method for assay of hyoscine N-butyl
bromide. Analytical Methods, 13(3):
369-380.
5. Koel, M. (2016). Do we need green analytical
chemistry?. Green Chemistry, 18(4):
923-931.
6. Chang, F., Zhang, X., Zhan, G., Duan, Y. and
Zhang, S. (2021). Review of methods for sustainability assessment of chemical
engineering processes. Industrial &
Engineering Chemistry Research, 60(1): 52-66.
7. Chinwong, D., Charaj, P., Panitsupakamol, P.,
Chankaew, T., Chinwong, S. and Saenjum, C. (2021). Local wisdom of miang
lifestyle and community for sustainable development in Northern Thailand. Sustainability, 13: 7381.
8. Lim, T. K. (2012). Garcinia dulcis. In edible medicinal and non-medicinal plants:
fruits. Springer Netherlands: pp. 35-40.
9. Purnama, H., Hidayati, N., Safitri, D. S. and
Rahmawati, S. (2017). Effect of initial treatment in the preparation of natural
indigo dye from Indigofera tinctoria. AIP
Conference Proceedings, 1855(1): 020022.
10.
Settheeworrarit, T., Hartwell, S. K., Lapanatnoppakhun, S., Jakmunee,
J., Christian, G. D. and Grudpan, K. (2005). Exploiting guava leaf extract as
an alternative natural reagent for flow injection determination of iron. Talanta, 68(2): 262-26.
11.
Grudpan, K., Hartwell, S. K., Wongwilai, W., Grudpan, S. and
Lapanantnoppakhun, S. (2011). Exploiting green analytical procedures for
acidity and iron assays employing flow analysis with simple natural reagent
extracts. Talanta, 84(5):
1396-1400.
12. Kanna, M., Somnam, S., Wongwilai, W. and
Grudpan, K. (2019). Towards green titration: Batchwise titration with reusable
solid sorbed indicators. Analytical
Sciences, 35(3): 347-350.
13. Pinyou, P., Kradtap Hartwell, S., Jakmunee,
J., Lapanantnoppakhun, S. and Grudpan, K. (2010). Flow Injection determination
of iron ions with green tea extracts as a natural chromogenic reagent. Analytical Sciences, 26(5): 619-623.
14. Siriangkhawut,
W., Ponhong, K. and Grudpan, K. (2019). A green colorimetric method using guava
leaves extract for quality control of iron content in pharmaceutical
formulations. Malaysian Journal of Analytical Sciences, 23(4): 595-603.
15. Supharoek, S.-A., Ponhong, K. and Grudpan, K.
(2017). A green analytical method for benzoyl peroxide determination by a
sequential injection spectrophotometry using natural reagent extracts from
pumpkin. Talanta, 171, 236-241.
16. analytical methodology using indian almond (Terminalia
Catappa L.) leaf extract for Insain, P., Khonyoung, S., Sooksamiti, P.,
Lapanantnoppakhun, S., Jakmunee, J., Grudpan, K., Zajicek, K. and Kradtap
Hartwell, S. (2013). Green determination of aluminum ion in waste water from
ceramic factories. Analytical Sciences, 29(6): 655-659.
17. Siriangkhawut, W., Khanhuathon, Y.,
Chantiratikul, P., Ponhong, K. and Grudpan, K. (2016). A green sequential
injection spectrophotometric approach using natural reagent extracts from
heartwood of Ceasalpinia sappan Linn. for Determination of Aluminium. Analytical Sciences, 32(3): 329-336.
18. Kiwfo, K., Wongwilai, W., Paengnakorn, P.,
Boonmapa, S., Sateanchok, S. and Grudpan, K. (2018). Noodle based analytical
devices for cost effective green chemical analysis. Talanta, 181: 1-5.
19. Siriangkhawut, W., Didpinrum, P.,
Khanhuathon, Y., Ponhong, K. and Grudpan, K. (2020). Small-scale
ultrasound-assisted extraction of phenolics from pomegranate peels and their
application as a natural reagent for the colorimetric assay of iron. Analytical Letters, 53(6): 887-904.
20. Kotchabhakdi, N., Seanjum, C., Kiwfo, K. and
Grudpan, K. (2021). A simple extract of Leucaena leucocephala (Lam.) de Wit
leaf containing mimosine as a natural color reagent for iron determination. Microchemical Journal, 162:
105860.
21. Weerasuk, B., Supharoek, S.-a., Grudpan, K.
and Ponhong, K. (2021). Exploiting crude betel nut (Areca catechu Linn.)
extracted solution as a natural reagent with sequential injection
spectrophotometry for iron analysis in rice samples. Journal of the Iranian Chemical Society, 19: 741-751.
22. Tapala, W., Chankaew, C., Grudpan, K. and
Rujiwatra, A. (2021). Silver-miang nanocomposites: A green, rapid and simple
approach for selective determination of nitrite in water and meat samples. Microchemical Journal, 162:
105879.
23. Ganranoo, L., Chokchaisiri, R. and Grudpan,
K. (2019). Simple simultaneous determination of iron and manganese by
sequential injection spectrophotometry using astilbin extracted from Smilax
china L. root. Talanta, 191:
307-312.
24. Jaikang, P., Paengnakorn, P. and Grudpan, K.
(2020). Simple colorimetric ammonium assay employing well microplate with gas
pervaporation and diffusion for natural indicator immobilized paper sensor via
smartphone detection. Microchemical
Journal, 152: 104283.
25. Sabarudin, A. and Indrayani, D. O. (2019).
Sequential Injection analysis for determination of lead(II) using extract of Caesalpinia
pulcherrima as a natural reagent. IOP
Conference Series. Materials Science and Engineering, 546(3): 032027.
26. Kiwfo, K., Woi, P. M., Saenjum, C. and
Grudpan, K. (2022). New designs of paper based analytical devices (PADs) for
completing replication analysis of a sample within a single run by employing
smartphone. Talanta, 236:
122848.
27. Kiwfo, K., Wongwilai, W., Sakai, T. N. T.,
Murakami, H.P. P., Phojuang, K., Kotchabhakdi, N. and Grudpan, K. (2020).
Simple natural material based microfluidic platforms with a smartphone
detection employing natural reagent for acidity assay. Journal Flow Injection Analysis,
37(1): 9-12.
28. Sateanchok, S., Wongwilai, W., Kiwfo, K. and
Grudpan, K. (2016). The assay of anionic surfactant employing thread based
analytical device with mobile phone. Journal
Flow Injection Analysis, 33(1): 5-7.
29. Sateanchok, S., Wangkarn, S., Saenjum, C. and
Grudpan, K. (2018). A cost-effective assay for antioxidant using simple cotton
thread combining paper based device with mobile phone detection. Talanta, 177: 171-175.
30. Chankaew, C., Tapala, W., Grudpan, K. and
Rujiwatra, A. (2019). Microwave synthesis of ZnO nanoparticles using longan
seeds biowaste and their efficiencies in photocatalytic decolorization of
organic dyes. Environmental Sciene
Pollution Research International, 26(17): 17548-17554.
31. Kiwfo, K., Yeerum, C., Issarangkura Na
Ayutthaya, P., Kesonkan, K., Suteerapataranon, S., Panitsupakamol, P.,
Chinwong, D., Paengnakorn, P., Chinwong, S., Kotchabhakdi, N., Saenjum, C.,
Vongboot, M. and Grudpan, K. (2021). Sustainable Education with local-wisdom
based natural reagent for green chemical analysis with a smart device:
experiences in Thailand. Sustainability, 13(20):
11147.
32. Center, C. C. A. R. (2021). CMU researcher
creates green innovation in chemical analysis from century-old wisdom of the
Fang people. Access from
https://www.cmu.ac.th/en/article/7b2719e8-86bc-4d0c-9205-9b4a40647597