Malaysian Journal of Analytical Sciences Vol 25 No 5 (2021): 791 - 807

 

 

 

 

METAL-ORGANIC FRAMEWORKS AS SORBENT- BASED EXTRACTION: A REVIEW

 

(Rangka Kerja Logam-Organik Sebagai Penjerap Berasaskan Pengekstrakan: Satu Ulasan)

 

Siti Sufiana Kamni1, Karimah Kassim1,2, Nur Sofiah Abu Kassim3, Nurul Auni Zainal Abidin3*

 

1Faculty of Applied Science

2 Institute of Science

Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

3 School of Chemistry and Environment, Faculty of Applied Science,

Universiti Teknologi MARA, Cawangan Negeri Sembilan,

Kampus Kuala Pilah, 72000 Kuala Pilah, Negeri Sembilan, Malaysia

 

*Corresponding author:  nurulauni@uitm.edu.my

 

 

Received: 27 July 2021; Accepted: 2 October 2021; Published:  25 October 2021

 

 

Abstract

Metal-organic frameworks (MOFs) are highly ordered porous crystalline structures and full of cavities. They are formed by inorganic centers (metal ion atoms or metal clusters) and organic linkers connected by covalent coordination bonds. Depending on the ratio of such precursors and the synthetic conditions, the characteristics of the resulting MOFs vary significantly, thus drifting into a countless number of interesting materials with unique properties. This review offers an overview on the current state of the use of MOFs in different microextraction configurations, in all cases covering extraction devices coated with (or incorporating) MOFs, with particular emphasis in their preparation.  Moreover, recent analytical applications reported from 2018 to 2020 will be discussed critically.  

 

Keywords:  metal-organic framework, microextraction method, sorbent, extraction

 

Abstrak

Rangka kerja logam-organik (MOFs) adalah struktur kristal berliang yang sangat tersusun dan berongga. MOFs dibentuk oleh logam pusat tak organik (atom ion logam atau kluster logam) dan penghubung organik yang dihubungkan oleh ikatan koordinasi kovalen. Bergantung pada nisbah bahan pemula dan keadaan sintetik, ciri-ciri MOFs yang dihasilkan berbeza-beza, sehingga menjadikan MOFs sebagai penarik kepada bahan penyerap dan bersifat unik. Ulasan ini memberikan gambaran umum mengenai keadaan semasa penggunaan MOFs yang berbeza-beza dalam konfigurasi pengekstrakan mikro yang meliputi kaedah pengekstrakan yang disaluti dengan (atau menggabungkan) MOFs, dengan penekanan khusus dalam penyediaannya. Tambahan pula, aplikasi analisis terkini yang dilaporkan dari tahun 2018 sehingga 2020 akan dibincangkan secara kritikal.

 

Kata kunci:  rangka kerja logam-organik, kaedah pengekstrakan mikro, bahan penyerap, pengekstrakan

 

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