Malaysian
Journal of Analytical Sciences Vol 25 No 1
(2021): 129 - 137
PREPARATION AND CHEMICAL COMPOSITION OF ALKALINE WATER FROM PLANT
COMBUSTION ASH
(Penyediaan dan Komposisi
Kimia Air Beralkali dari Abu Loji Pembakaran)
Pairin Pongsa and Napa Tangtreamjitmun*
Department
of Chemistry, Faculty of Science,
Burapha
University, Bangsaen, Chonburi, 20131 Thailand
*Corresponding
author email address: napa@buu.ac.th
Received: 9 December 2020;
Accepted: 18 January 2021; Published: 20
February 2021
Abstract
The alkaline water prepared from burning
natural materials into ash and submersing the ash in water was studied. The
combustion time and the percentage of ash obtained for each material were
different. The major chemical components of the ash were identified by Fourier
transform infrared spectroscopy. The main functional groups found were
carbonate and hydroxide. The alkaline water which had a pH of 11-12 was
filtered and studied for its chemical composition. The alkalinity in terms of
hydroxide, carbonate and bicarbonate species was determined by acid titration.
The sodium, potassium, calcium and magnesium content were determined by
inductively coupled plasma optical emission spectrophotometer. The major
cations found were potassium and sodium. The concentrations and pH of the
alkaline water that would be obtained after dilution should be suitable for
human consumption although further medical testing is required.
Keywords: alkaline water, lye water, ash, alkalinity
Abstrak
Air
beralkali telah disediakan dari pembakaran bahan semulajadi kepada abu dan
kebolehan tenggelan abu di dalam air telah dikaji. Masa pembakaran dan peratus
abu yang diperolehi bagi setiap bahan adalah berbeza. Komponen kimia utama bagi
abu telah dikenalpasti menggunakan spektroskopi inframerah transformasi
Fourier. Kumpulan berfungsi utama yang ditemui adalah karbonat dan hidroksida.
Air beralkali yang mempunyai nilai pH 11-12 telah dituras dan dikaji
komposisinya. Sifat kealkalian seperti spesis hidroksida, karbonat dan bikarbonat
telah ditentukan melalui pentitratan asid. Kandungan sodium, kaliam, kalsium
and magnesium telah di analisis menggunakan spektrofotometer sebaran optikal –
plasma gandingan aruhan. Kation utama yang dijumpai adalah kalium dan sodium.
Kepekatan dan nilai pH air beralkali diperolehi selepas pencairan sesuai bagi
penggunaan manusia meskipun ujian perubatan lanjutan masih diperlukan.
Kata kunci: air beralkali, air abu, abu, kealkalian
References
1.
Fu, B. X. (2008). Asian
noodles: History, classification, raw materials, and processing. Food Research
International, 41: 888-902.
2.
Ignacio, R. M., Joo, K.
B., and Lee, K. J. (2012). Clinical effect and mechanism of alkaline reduced
water. Journal of Food and Drug Analysis, 20(1): 394-397.
3.
Shirahata, S., Hamasaki,
T. and Yeruya, K. (2012). Advanced research on the health benefit of reduced
water. Trends in Food Science & Technology, 23: 124-131.
4.
APHA. (2012). No. 2320 B:
Titration Method. Standard Methods for the Examination of Water and Wastewater.
22nd ed. American Public Health Association, Washington, D.C.
5.
Berg, M.G. Fertilizer
guide. (1982). Using Wood Ashes in the Home Garden. Oregon state university
extension service. https://ir.library.oregonstate.edu/downloads/2j62s561s
[Access online 15 May 2019].
6.
Rafat, S. (2012).
Utilization of wood ash in concrete manufacturing. Resources Conservation
and Recycling, 67: 27-33.
7.
Martins, F. M., Martins
J. M., Ferracin L. C. and Cunha, C. J. (2007). Mineral phases of green liquor
dregs, slaker grits, lime mud and wood ash of a Kraft pulp and paper mill. Journal
of Hazardous Materials, 147: 610-617.
8.
Adler, H. H. and Kerr, P.
F. (1963). Infrared absorption frequency trends for anhydrous normal
carbonates. The American Mineralogist, 48: 124-137.
9.
Misra, M. K., Ragland,
K.W. and Baker, A. J. (1993). Wood ash composition as a function of furnace
temperature. Biomass and Bioenergy, 4(2): 103-116.
10.
US-EPA. (1994). EPA's
drinking water glossary: A dictionary of technical and legal terms related to
drinking water, EPA810-B-94-006, Environmental Protection Agency, Washington,
DC. USA.