Malays. J. Anal. Sci. Volume 30 Number 2 (2026): 1710

 

Research Article

 

Degradation of methyl orange by Fe(III) TAML/H2O2 catalytic system: Response surface analysis of process parameters

 

Siti Nur Khairunnisa Mahassan, Nabilah Ismail*, and Nora Salina Md Salim

 

Faculty of Science and Marine Environment, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia

 

*Corresponding author: nabilah.i@umt.edu.my

 

Received: 23 September 2025; Revised: 16 January 2026; Accepted: 23 February 2026; Published: 30 April 2026

 

Abstract

Methyl Orange (MO) is a synthetic azo dye widely used in textile and laboratory applications and is classified as a micropollutant due to its toxicity, persistence, and resistance to conventional wastewater treatment processes. In this study, the catalytic degradation of MO was investigated using a homogeneous Fe(III)-TAML/H₂O₂ system, with emphasis on evaluating the effects and interactions of key process parameters using Response Surface Methodology (RSM). A Central Composite Design (CCD) was employed to evaluate the effects and interactions of four independent variables, namely pH, stirring speed, catalyst ratio, and dye ratio, on the percentage degradation of MO. The developed quadratic model exhibited strong statistical significance (R² = 0.9178) and revealed significant interaction and non-linear effects among the operating parameters. Based on the model-predicted conditions, high MO degradation (96.43%) was observed at pH 9.5, stirring speed 500 rpm, catalyst ratio 1, and dye ratio 100. Experimental validation under these conditions achieved 92.33% degradation, with a deviation of less than 5% from the predicted value, confirming the model's reliability. Across the experimental domain, MO degradation efficiencies ranged from approximately 5% to over 94%, depending on operating conditions. The results demonstrated that the Fe(III)-TAML/H₂O₂ catalytic system was a highly efficient and environmentally sustainable advanced oxidation process (AOP) for the removal of azo dyes. The conditions identified in this study provided valuable quantitative guidance for the application of this catalytic system in practical wastewater treatment, particularly for dye-contaminated effluents.

 

Keywords: response surface methodology, degradation, methyl orange, catalytic system

 


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