The
Malaysian Journal of Analytical Sciences Vol 17 No 2 (2013): 272 – 275
SUBCRITICAL WATER EXTRACTION OF
MONOSACCHARIDES FROM OIL PALM FRONDS HEMICELLULOSES
(Pengekstrakan
Air Subgenting Daripada Monosakarida Dari Hemiselulosa
Pelepah Kelapa Sawit)
R., Norsyabilah, S. Sabiha Hanim*, M. H., Nor Suhaila, A. Noraishah, A.K., Siti Kartina
Faculty
of Applied Sciences,
Universiti
Teknologi MARA, 40450 Shah Alam, Selangor D.E. , Malaysia
*Corresponding author: sabihahanim@salam.uitm.edu.my
Abstract
Oil palm plantations in Malaysia generate more than 36
million tones of pruned and felled oil palm fronds (OPF) and are generally
considered as waste. The composition of monosaccharide in oil palm frond can be
extracted using hydrothermal treatment for useful applications. The objectives
of this study were to quantify the yield of monosaccharides at various reaction conditions; temperature 170 °C to 200 °C, pressure from 500
psi to 800 psi, reaction time from 5 to 15 min using subcritical water
extraction and to determine the composition of oil palm
frond hemicelluloses at optimum condition. The monosaccharides composition of
oil palm frond hemicellulose were
analysed using
High Performance Liquid Chromatography (HPLC). The highest yield of
monosaccharides can be extracted from OPF at temperature of
190 ºC, pressure of 600 psi
and 10 min of contact time which is xylose the most
abundant composition (11.79 %) followed with arabinose (2.82 %), glucose (0.61
%) and mannose (0.66 %).
Keywords: oil
palm fronds; monosaccharide; subcritical water extraction; HPLC
References
1. Abu Hassan.,
Ishida, M., Mohd, I., Shukri., Ahmad Tajuddin, Z. (2000). Oil-palm fronds as a roughage feed source
for ruminants in Malaysia. Research division.
Malaysian Agriculture Research and Development Institute (MARDI).
2. Mior,
AK., Mohd Zahari., Mohd Rafein, Z., Hidayah, A., Mohd Noriznan, M., Jailani,
S., Yoshihito, S., Mohd Ali H. (2012). Renewable sugars from oil palm frond juice as
an alternative novel fermentation feedstock for value-added products. Bioresource Technology, 110: 566–571.
3. Matsunaga,
M., Matsui, H., Otsuka, Y., Yamamoto, S.
(2008). Chemical conversion of wood by treatment in semi-batch reactor with
subcritical water. Journal of
Supercritical Fluids, 44: 364-369.
4. Xiao,
B., Sun, X.F., RunChans, Sun. (2001). Chemical, structural and thermal
characterizations of alkaline-soluble and hemicelluloses, and cellulose from
maize stems, rye straw and rice. Polymer
Degradation and Solubility, 74: 307-319.
5. Tsuyoshi,
S., Hiroyuki, I., Shinichi, Y., Takashi, E., Shigeki., Sawayama. (2008).
Combining hot-compressed water and ball milling pretreatments to improve the
efficiency of the enzymatic hydrolysis of eucalyptus. Biotechnology for fuels, 186: 1754-5834.
6. Vuorinen, T., Alén, R. (1999). Analytical Methods in Wood Chemistry, Pulping and Papermaking. Journal of carbohydrate, 38–75.
7. Kronholm, J., Hartonen, K. & Riekkola, M.(2007).
Analytical extractions with water at elevated temperatures and pressures. Trends
in Analytical Chemistry, 26
8. Buranov AU, Mazza G (2010). Extraction and characterization of
hemicelluloses from flax shives by different methods. Carbohydr Polym 79: 17–25.
9. Sabiha, S.H., Norsyabilah, R., Nor Suhaila, M.H.,
Noraishah, A., Siti Kartina, A. K.(2012). Effects of temperature, time and
pressure on the hemicelluloses yield extracted using subcritical water
extraction. Procedia Engineering, 42:
616-619.
10. Alpinar, O., Levent, O., Sabanci, S., Uysal, R. S., Sapci B. (2011).
Optimization and comparison of dilute acid pretreatmentof selectedagricultural
residues for recovery of xylose. Peer-reviewed Bioresources.
11. Wang, K., Xin, J. J., Xu, F., Cang, S. R., Baird, M. S. (2010). Influence
of steam pressure on the physicochemical properties of degraded hemicelluloses
obtained from steam exploded Lespedeza stalk. Peer-reviewed Bioresource.
12. Cai, W., Gu, X. & Tang J. (2008). Extraction, purification, and
characterization of the polysaccharides from Opuntia milpa alta. Carbohydrate Polymers, 71: 403-410.
13. Itziar, E., Cristina, S., Inaki, M., Jalel, L.
(2012). Effect of alkaline and autohydrolysis processes on the purity of
obtained hemicelluloses from corn stalk. Bioresource
technology, 103: 239-248.