The Malaysian Journal of Analytical Sciences Vol 17 No 1 (2013): 171 – 175

 

 

 

GLYCINE AS ALTERNATIVE FUEL IN MAKING HYDROTALCITE COMPOUND BY MEANS OF COMBUSTION METHOD

 

(Glisin Sebagai Bahanapi Alternatif Dalam Pembuatan Sebatian Hidrotalsit

Melalui Kaedah Pembakaran)

 

Shamsudin I.K1, Helwani Z1,2, Abdullah A.Z1, Wiheeb A.D1,3, Othman M.R1*

 

1School of Chemical Engineering,

Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang, Malaysia

2Department of Chemical Engineering,

Riau University, Pekanbaru 28293, Indonesia

3Department of Chemical Engineering, College of Engineering,

University of Tikrit, Salah ad Din, Iraq

 

*Corresponding author: chroslee@eng.usm.my

 

 

Abstract

Hydrotalcite is anion compound capable of exchanging ions; it has the potential as a catalyst and adsorbent for variety of applications. Hydrotalcite can be prepared through several approaches, depending on the specific need and the characteristics of the compound. In this study, hydrotalcite was prepared through combustion method using glycine as fuel for the first time. Glycine was selected as opposed to urea so that hydrotalcite is safe for use in food processing or health. Hydrotalcite that was successfully obtained via combustion technique using glycine as fuel showed interesting characteristics. The compound demonstrated high thermal endurance and highest alkalinity, which suited the application for biodiesel production from vegetable oil and hydrogenation in the making of fats. However, the surface area was low in comparison with the same compound obtained from co-precipitation and sol-gel techniques.

 

Keywords: hydrotalcite, catalyst, sol gel technique, combustion method, co-precipitation method, bio-diesel

 

References

1.       ManasseE. (1915). Rocce eritree e di aden della collezione issel. Atti Soc. oscanaScNat., ProcVerb2492

2.       Feitknecht, W. (1942). The Formation of Double Hydroxide between Bivalent and Trivalent Metals Helv. Chim.Acta 25: 131 and 555.

3.       Almann, R. (1968).The crystal structure of pyroaurite, Acta Cryst. 24: 972

4.       Cavani, F., Trifiro, F., Vaccari A. (1991). Hydrotalcite-type anionic clays: preparation, properties and applications. Catal. Today 11: 173.

5.       Oesten, R. and Bohm, H. (1993). Ionic mobility in basic double salts. Part 1: Hydrotalcites.Solid State Ionics 62: 199.

6.       Ookubo A, Ooi HHayashi K. (1993). Preparation and phosphate ion-exchange properties of a hydrotalcite-like compound. Langmuir 9:1418.

7.       Reichle, W.T. (1986). Synthesis of anionic clay minerals (mixed metal hydroxides, hydrotalcite). Solid State Ionics. 22: 135 – 141.

8.       Lee, W.F., Chen Y.C. (2006). Effects of intercalated hydrotalcite on drug release behaviour for poly(acrylic acid-co-N-isopropyl acrylamide)/intercalated hydrotalcite hydrogels. Eur Polymer J 42:1634.

9.       Aramendia, M.A., Aviles, Y., Benitez, J.A., Borau, V., Jimenez, C., Marinas, J.M.,Ruiz, J.R. and Urbano, F.J. (1999). Comparative study of Mg/Al and Mg/Ga layered double hydroxides. Microporous and Mesoporous Materials 29: 319 – 328.

10.    Yong, Z. and Rodrigues, A. E. (2002). Hydrotalcite – like compounds as adsorbents for carbon dioxide. Energy Conversion and Management 43 :1865 – 1874.

11.    Yamamoto, T., Kodama, T., Hasegawa, N., Tsuji, M. and Tamaura, T. (1995). Synthesis of hydrotalcite with high layer charge for CO2 adsorbent. Energy Conversion Management 36 : 637 – 640.

12.    Ding, Y. and Alpay, E. (2000). Equilibria and kinetics of CO2 adsorption on hydrotalcite adsorbent. Chemical Engineering Science 55: 3461 – 3474.

13.    Othman, M.R., Rasid, N.M., Fernando, W.J.N. (2006). Effects of thermal treatment on the micro-structures of co-precipitated and sol-gel synthesized (Mg-Al) hydrotalcites. Microporous and Mesoporous Materials 93: 23-28.

14.    Othman M.R., Fernando W.J.N, Kim, J. (2009). The conversion of an organometallic compound into an intercalated thin-layer amorphous structure. Appl. Organometal Chem. 23: 403-408.

15.    Lopez – Salinas, E., Torres – Garcia, E. and Garcia – Sanchez, M.(1997). Thermal behavior of hydrotalcite – like [Mg1-x Ga x (OH)2] (CO3)x/2 . mH2O as a function of Galium content. Journal Physical Chemistry Solids. 58(6): 919 – 925.

16.    Fetter, G., Hernandez, F., Maubert, A.M., Lara, V.H., Bosch, P. (1997). Microwave irradiation effect on hydrotalcites synthesis, J. Porous Mater. 4:27

17.    Yang, W., Kim, Y., Liu Paul, K.T., Tsotsis, T.T. and Sahimi, M. (2002). A study by in situ techniques of the thermal evolution of the structure of a Mg – Al – CO3 layered double hydroxide. Chemical Engineering Science 57 : 2945 – 2953.

18.    Patil, K.C., Aruna, S.T., Ekambaram, S. (1997). Combustion synthesis, Solid State Mater. Sci. 2: 158.

19.    Cruz, D., Bulbulian, S. (2003). Synthesis of lithium silicate tritium breeder powders by a modified combustion method, J. Nucl. Mater. 312: 262.

20.    Constantino, U., Mamottini, F., Nocchetti, M., Vivani, R. (1998). New synthetic routes to hydrotalcite-like compounds-characterisation and properties of obtained materials, Eur. J. Inorg. Chem. 10:1439.

21.    Diez, V.K., Apesteguia, C.R., and J.I. Di Cosimo (2003). Effect of the chemical composition on the catalytic performance of MgyAlOx catalysts for alcohol elimination reactions. J. Catal. 215: 220-233.

22.    Mistra, C., Perrotta, A. (1992). Composition and properties of synthetic hydrotalcites, Clays Clay Miner. 40: 145.

23.    Kagunya, W., Hassan, Z., Jones, W. (1996). Catalytic Properties Of Layered Double Hydroxides and Their Calcined Derivatives, Inorg. Chem 35: 5970.

24.    Prinetto, F., Ghiotti, G., Graffin, P. and Tichit, D. (2000). Synthesis and characterization of sol gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples. Microporous and Mesoporous Materials 39 : 229 – 247.

25.    Cantrell, D.G., Gillie, L.J., Lee, A.F., Wilson, K. (2005). Structure-reactivity correlations in MgAl hydrotalcite catalyst for biodiesel synthesis, Applied Catalysis A: Gen. 287, 183-190.

26.    Erickson, K.L., T.E. Bostrom, and R.L. Frost (2004). A study of structural memory effects in synthetic hydrotalcites using environmental SEM. Materials Letters, 59(2-3): 226-229.

27.    Davila, V., Lima, E., Bulbulian, S., Bosch, P. (2008). Mixed Mg(Al)O oxides synthesized by the combustion method and their recrystallization to hydrotalcites, Microporous and Mesoporous Materials 107: 240-246.

28.    Martunus, Othman, M.R., Fernando, W.J.N. (2011). Elevated temperature CO2 capture via reinforced metal hydroxide, Microporous and Mesoporous Materials, 138:110-117.

 

Previous                    Content                    Next