The
Malaysian Journal of Analytical Sciences Vol 16 No 3 (2012): 241 – 246
INCORPORATION OF
CYCLOTRIPHOSPHAZENES AS PENDANT GROUPS TO THE SAGO NETWORK
(Percantuman Siklofosfazena
sebagai Kumpulan Terikat kepada Rantaian Sagu)
Zainab Ngaini*1, Khairul Aidil Azlin Abd
Rahman2, Nazlina Shaari2,
Hasnain Hussain1,
Norhaizat
Sundin2, Teng Jingxin1
1Department of Chemistry, Faculty of Resource Science and
Technology,
2Department
of Design Technology, Faculty of Applied and Creative Arts,
Universiti Malaysia
Sarawak, 94300, Kota Samarahan, Sarawak
*Corresponding author: nzainab@frst.unimas.my
Abstract
Cyclotriphosphazene-incorporated
sago wastes as pendant groups have been prepared and structurally characterized
using FT-IR and SEM. The chemically modified
sago wastes composite was applied with binders and developed as sound absorbing
panels. These panels are a class of
organic-inorganic based materials that exhibit excellent fire retardant
properties. Sound absorbance test has given a higher value at 250, 500 and 2000
Hz, which indicates the suitability of the panel for used in medium frequency.
The panel was 51% lighter compared to fiberboard. The function and basic
manufacturing of sound absorbers products was aligned with the present products
in the market.
Keywords: sago waste, cyclotriphosphazene, fire
retardant; sound absorber panel
References
1. Singhal
R. S., Kennedy, J. F., Gopalakrishnan, S. M., Kaczmarek, A., Knill, C. J. &
Akmar P. F., 2008. Industrial production, processing and utilization of sago
palm-derived products. Journal of Carbohydrate Polymers 72:1-20.
2.
Bujang,
K, Apun, K. & Salleh, M. A. 1996. A
Study in the Production and Bioconversion of Sago Waste. In Sago-The future Source of Food and Feed,
edited by Jose C, Rasyad A, Riau University Press, Indonesia: 195-201.
3.
Inoue,
K., Nakamura, H., Ariyoshi, S., Takagi, M. & Tanigaki, T. 1989. Heat
Resistance Polymers Prepared from [(4′-(2-Vinyl)-4-Biphenylyl)Oxy]
Pentachlorocyclo-triphosphazene. Macromolecules 22(12): 4466-4469.
4. Selvaraja, I. I.
& Chandrasekhar, V. 1997. Copolymerization of
2-(4-vinyl-4-biphenylyloxy)pentachlorocyclotriphosphazene with Acrylate and
Methacrylate Monomers. Polymer 38(14): 3617-3623.
5. Muraki, T., Ueta, M., Hara, E. & Inoue, K. 2004. Enhancement
of thermal stability of polystyrene
and poly(methyl methacrylate) by cyclotriphosphazene. Polymer Degradation and
Stability 84: 87- 93
6.
Liu, R. & Wang, X. 2009. Synthesis, Characterization,
Thermal Propereties and Flame Retardancy of a Novel Nonflammable
Phosphazene-Based Epoxy Resin. Polymer Degradation and Stability 94(4): 617-624.
7.
Kruszynski, R., Siwy, M., Iwona, P.-C.,
& Trzesowska, A. 2006. A New
Regioselective Method of Macrobicyclic Schiff Bases Synthesis. Inorganica Chimica Acta 359: 649-658.